Solved: An electrochemical cell consists of a silver metal

Chapter 11, Problem 11.117

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An electrochemical cell consists of a silver metal electrode immersed in a solution with [Ag1] 5 1.00 M separated by a porous disk from a compartment with a copper metal electrode immersed in a solution of 10.00 M NH3 that also contains 2.4 3 1023 M Cu(NH3)4 21. The equilibrium between Cu21 and NH3 is: Cu21 1aq2 1 4NH3 1aq2mCu1NH32 4 21 1aq2 K 5 1.0 3 1013 and the two cell half-reactions are: Ag1 1 e2 h Ag % 5 0.80 V Cu21 1 2e2 h Cu % 5 0.34 V Assuming Ag1 is reduced, what is the cell potential at 25C?

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