Compare Figs. 14.38 and 14.40. Why are they different?

Chapter 14, Problem 14.5

(choose chapter or problem)

Compare Figs. 14.38 and 14.40. Why are they different? Because B2 is known to be paramagnetic, the p2p and s2p MOs must be switched from our first prediction. What is the rationale for this? Why might one expect the s2p to be lower in energy than the p2p? Why cant we use diatomic oxygen to help us decide whether the s2p or p2p is lower in energy?

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