Answer: Values of measured bond energies may vary greatly

Chapter 14, Problem 14.81

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Values of measured bond energies may vary greatly depending on the molecule studied. Consider the following reactions: NCl3(g) 88n NCl2(g) 1 Cl(g) DH 5 375 kJ/mol ONCl(g) 88n NO(g) 1 Cl(g) DH 5 158 kJ/mol Rationalize the difference in the values of DH for these reactions, even though each reaction appears to involve the breaking of only one NOCl bond. (Hint: Consider the bond order of the NO bond in ONCl and in NO.)

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