Answer: A study was made of the effect of the hydroxide

Chapter 15, Problem 15.29

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A study was made of the effect of the hydroxide concentration on the rate of the reaction I2(aq) 1 OCl2(aq) 88n IO2(aq) 1 Cl2(aq) The following data were obtained: [I2]0 (mol/L) [OCl2]0 (mol/L) [OH2]0 (mol/L) Initial Rate (mol L21 s21) 0.0013 0.012 0.10 9.4 3 1023 0.0026 0.012 0.10 18.7 3 1023 0.0013 0.0060 0.10 4.7 3 1023 0.0013 0.018 0.10 14.0 3 1023 0.0013 0.012 0.050 18.7 3 1023 0.0013 0.012 0.20 4.7 3 1023 0.0013 0.018 0.20 7.0 3 1023 Determine the rate law and the value of the rate constant for this reaction.

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