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The rate law for the reaction BrO3 2(aq) 1 3SO3 22(aq) 88n

Chemical Principles | 8th Edition | ISBN: 9781305581982 | Authors: Steven S. Zumdahl ISBN: 9781305581982 176

Solution for problem 15.67 Chapter 15

Chemical Principles | 8th Edition

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Chemical Principles | 8th Edition | ISBN: 9781305581982 | Authors: Steven S. Zumdahl

Chemical Principles | 8th Edition

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Problem 15.67

The rate law for the reaction BrO3 2(aq) 1 3SO3 22(aq) 88n Br2(aq) 1 3SO4 22(aq) is Rate 5 k[BrO3 2][SO3 22][H1] The first step in a proposed mechanism is SO3 22(aq) 1 H1(aq) 88n HSO3 2(aq) Fast The second step is rate determining. Write a possible second step for the mechanism.

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C117 Chapter 13 Notes- Chemical Kinetics and Rates of Reactions 3-4-16  Homogeneous reaction- reactants in same phase, ie. combustions, acid/base  Heterogeneous reaction- reactants in different phases, ie. oxidation of metal o Surface area can strongly influence rates  Reaction rate- measure of how fast reaction occurs +2 +2 o Ex. 2 )6 + →3 2 )5 3 + 2 o −Δ o Reaction rate = Δ = average rate over time change Δ  Negative if dealing with reactant, positive if product  Depends on concentrations of reagents o If we make Δ

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Chapter 15, Problem 15.67 is Solved
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Textbook: Chemical Principles
Edition: 8
Author: Steven S. Zumdahl
ISBN: 9781305581982

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The rate law for the reaction BrO3 2(aq) 1 3SO3 22(aq) 88n