Rationalize the following differences in physical
Chapter 16, Problem 16.24(choose chapter or problem)
Rationalize the following differences in physical properties in terms of intermolecular forces. Compare the first three substances with each other, compare the last three with each other, and then compare all six. Can you account for any anomalies? Substance bp (8C) mp (8C) DHvap (kJ/mol) Benzene, C6H6 80 6 33.9 Naphthalene, C10H8 218 80 51.5 Carbon tetrachloride 76 223 31.8 Acetone, CH3COCH3 56 295 31.8 Acetic acid, CH3CO2H 118 17 39.7 Benzoic acid, C6H5CO2H 249 122 68.2
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