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Solve each equation and check your proposed | Ch 2.3 - 53

Introductory & Intermediate Algebra for College Students | 4th Edition | ISBN: 9780321758941 | Authors: Robert F. Blitzer ISBN: 9780321758941 177

Solution for problem 2.1.256 Chapter 2.3

Introductory & Intermediate Algebra for College Students | 4th Edition

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Introductory & Intermediate Algebra for College Students | 4th Edition | ISBN: 9780321758941 | Authors: Robert F. Blitzer

Introductory & Intermediate Algebra for College Students | 4th Edition

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Problem 2.1.256

Solve each equation and check your proposed solution in Exercises 4758. 0.4(2z 6) 0.1 0.5(2z 3)

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4/4/16 EXAMAPRIL14 th Ø 4/12NickTreichishostingareviewsession@415pminFulmer125 Ø 4/12Finneganishostingareviewsessioninthepit@7 Ø 4/11@515theChemclubishostingareviewsession AXE • • n=thenumberofbondinggroupsonthecentralatom • m=thenumberoflonepairsonthecentralatom • ANYtypeofbond(single,double,triple)isonebondinggroup • n+m=thenumberofelectrongroupsonthecentralatom ElectronGeometry • Thenumberofelectrongroupsdeterminesthis • Thereareonly5,seetable10.1 • Determinestheidealbondangles-elementstryandarrangethemselvesasfar awayfromeachotheraspossiblebecausetheelectronsrepulsethemselves MolecularGeometry(shape)-electrongeometryandthenumberoflonepairs determinethemoleculargeometry • Themolecularshape,thebonpolarities,andtheformalchargedistribution determinethemolecularpolarity 4/6/16 BondAngles • ElectronGeometrydeterminestheidealbondangles(theyareapproximate) Linear:180degreeangles Triganolplanar:120degreeangles Tetrahedral:109.5degreeangles Trigonalbipyramidal:90,120degreeangles Octahedral:90degreeangles • Lonepairstakeupmorespacethanbondingpairs • Doublebondstakeupmorespacethanasinglebonds • ImportantNote:Whendealingwithresonancestructures,theamountof spacethe“rotating”doublen=bondtakesupisnegligiblebecauseitis technicallyalldoublebonds ▯ • ElectronGeometry:TriganolBipyramidal • ℎ:Linearduetothe180degreeangle HowdowedothebondanglesforthismoleculeByusingtheideathatdouble bondstakeupmorespacethanasingle,andlonepairstakemorespacethanbonds • OctahedralElectronGeometry: ▯ ▯ • Molecularshape:squareplanar,duetothe90degreeangle • BondanglesforF-Xe-Fis90degrees • ElectronGeometry:Tetrahedral • MolecularShape:Triganolpyramidal • BondAnglesforH-N-Hislessthan109.5becausethelonepairwillmakethe anglesmallerthanthatofanormaltetrahedralmolecule NoticehowitisTetrahedralwiththelonepair,fortheshapethelonepairisnot drawn PolarandNon-PolarMolecules • Somethingispolarifithasanegativesideandanonpolarside • Inmoleculesthisisdeterminedbysymmetryaroundthecentralatom • If a molecule is symmetric (by polar bonds)around the central atom, the charges cancel eachother out • If the molecule is not semetric(by polar bonds) than the molecule is polar • A numeric measure of polarity is the Dipole moment(μ) • The more polar a molecule the larger the dipole moment • Is ▯ polar or non-polar Non-polar • Is ▯polar or non polar Non polar • Is ▯olar or non polar Polar • Look at the bonds and the way the bonds are arranged to see if they are polar or not! ValenceBondTheory • Acovalentbondisproducedbytheoverlapoforbitalsintheregion betweenthetwoatoms • Thegreatertheoverlap,thestrongerthebond. • But,theatomicorbitalsdonotalwayspointintherightdirectionsto producetheshapesthatthemoleculesaresupposedtohave Toexplainthis,itisassumedthattheatomicorbitalsaremixedtoproduce‘hybrid’ orbitalsthatpointinthecorrectdirection. • Hybridorbitalsarenamedfortheorbitalsthatcontributetothem.For Example isacombinationofonesorbitalandtwoporbitals • ImportantNote:Allorbitalsthataremixedmustcomefromthesame shell.ForExample3pand3scanbehybrids,but2pand4scannotbe combinedtogether. • The▯totalnumberoforbitalsisunchanged(Therewillbe2orbitals,three orbitalsandsoon) EachhybridhasitsownGeometryassociatedwithit,asshownbelow NoticehowforthegroundstateofCarbonthe2sorbitalisfull,butthe2porbitalis not▯evenhalffull,thismakescarbonunstablesothetwoorbitalscombinetoform ,makingcarbonstable • Singlebondsareformedbyoverlappingorbitalsinbetweenthe atoms.Thesebondsarecalledsigma(σ)bonds. • Doubleandtriplebondsalsocontainaσ-bondbutthesecond(andthird bond)cannotformdirectlybetweentheatoms(becausethereisalreadya pairofelectronsthere) • Theadditionalbondsareformedbyunhybridizedp-orbitalsthat overlapintheareastoeithersideofthesigmabond.Thesebondsare calledpi(π)bonds. • Adoublebondconsistsofaσ-bondandaπ-bond. • Atriplebondconsistsofaσ-bondandtwoπ-bonds. ThisDiagramshouldhelpyouvisualizetheprincipalofsigmaandpibonds

Step 2 of 3

Chapter 2.3, Problem 2.1.256 is Solved
Step 3 of 3

Textbook: Introductory & Intermediate Algebra for College Students
Edition: 4
Author: Robert F. Blitzer
ISBN: 9780321758941

This textbook survival guide was created for the textbook: Introductory & Intermediate Algebra for College Students, edition: 4. Since the solution to 2.1.256 from 2.3 chapter was answered, more than 236 students have viewed the full step-by-step answer. The full step-by-step solution to problem: 2.1.256 from chapter: 2.3 was answered by , our top Math solution expert on 12/23/17, 04:54PM. This full solution covers the following key subjects: . This expansive textbook survival guide covers 119 chapters, and 11220 solutions. The answer to “Solve each equation and check your proposed solution in Exercises 4758. 0.4(2z 6) 0.1 0.5(2z 3)” is broken down into a number of easy to follow steps, and 16 words. Introductory & Intermediate Algebra for College Students was written by and is associated to the ISBN: 9780321758941.

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Solve each equation and check your proposed | Ch 2.3 - 53