Answer: When toluene (C6H5CH3) reacts with chlorine gas in

Chapter 21, Problem 21.130

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When toluene (C6H5CH3) reacts with chlorine gas in the presence of an iron(III) catalyst, the product is a mixture of the ortho and para isomers of C6H4ClCH3. However, when the reaction is light-catalyzed with no Fe31 catalyst present, the product is C6H5CH2Cl. Explain.

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