Which of the solutions in Exercise 23 shows the least change in pH upon the addition of acid or base? Explain.
Chapter 7: F urther Reactions of H aloalkanes A. Solvolysis of Tertiary a nd econdary Haloalkanes a. The rate of the S 2 reaction diminishes drastically when the reacting center N changes from primary to secondary t o ertiary i. Only for bimolecular substitution b. Solvolysis- t ransformation where a substrate undergoes substitution by solvent molecules i. Hydrolysis- when the solvent is water c. The order of reactivity in N 1 reactions is reversed from N 2 reactions i. Primary halides are now very