Solution: The rate law for the decomposition of ozone to

Chapter 13, Problem 13.57

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The rate law for the decomposition of ozone to molecular oxygen 2O3(g) 3O2(g) is rate 5 k [O3] 2 [O2] The mechanism proposed for this process is O O3 k2 2O2 O3 k1 k 1 O O 2 Derive the rate law from these elementary steps. Clearly state the assumptions you use in the derivation. Explain why the rate decreases with increasing O2 concentration.

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