Solution: The following data were collected for the reaction

Chapter 13, Problem 13.74

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The following data were collected for the reaction between hydrogen and nitric oxide at 7008C: 2H2(g) 1 2NO(g) 2H2O(g) 1 N2(g) Experiment [H2] [NO] Initial Rate (M/s) 1 0.010 0.025 2.4 10 6 2 0.0050 0.025 1.2 10 6 3 0.010 0.0125 0.60 10 6 (a) Determine the order of the reaction. (b) Calculate the rate constant. (c) Suggest a plausible mechanism that is consistent with the rate law. (Hint: Assume that the oxygen atom is the intermediate.)

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