At a certain elevated temperature, ammonia
Chapter 13, Problem 13.129(choose chapter or problem)
At a certain elevated temperature, ammonia decomposes on the surface of tungsten metal as follows: NH3 1 2N2 1 3 2H2 The kinetic data are expressed as the variation of the half-life with the initial pressure of NH3: P (mmHg) 264 130 59 16 t1 456 228 102 60 2 (s) (a) Determine the order of the reaction. (b) How does the order depend on the initial pressure? (c) How does the mechanism of the reaction vary with pressure? (Hint: You need to use the equation in 13.124 and plot log t1 2 versus log P.)
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