Solved: (a) Troutons rule states that the ratio of the
Chapter 17, Problem 17.48(choose chapter or problem)
(a) Troutons rule states that the ratio of the molar heat of vaporization of a liquid (DHvap) to its boiling point in kelvins is approximately 90 J/K ? mol. Use the following data to show that this is the case and explain why Troutons rule holds true: tbp(8C) DHvap(kJ/mol) Benzene 80.1 31.0 Hexane 68.7 30.8 Mercury 357 59.0 Toluene 110.6 35.2 (b) Use the values in Table 11.6 to calculate the same ratio for ethanol and water. Explain why Troutons rule does not apply to these two substances as well as it does to other liquids
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