Consider the reactions Ni21 1aq2 1 6NH3 1aq2 h Ni1NH32 6 21 1aq2 (1) Ni21 1aq2 1 3en1aq2

Chapter 17, Problem 17.119

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Consider the reactions Ni21 1aq2 1 6NH3 1aq2 h Ni1NH32 6 21 1aq2 (1) Ni21 1aq2 1 3en1aq2 h Ni1en2 3 21 1aq2 (2) where en 5 H2NiCH2iCH2iNH2 The DH values for the two reactions are quite similar, yet Kreaction 2 . Kreaction 1. Explain.

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