The complex ion Cu(H2O)6 21 has an absorption maximum at

Chapter 21, Problem 21.70

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The complex ion Cu(H2O)6 21 has an absorption maximum at around 800 nm. When four ammonias replace water, Cu(NH3)4(H2O)2 21, the absorption maximum shifts to around 600 nm. What do these results signify in terms of the relative field splittings of NH3 and H2O? Explain.

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