Although the DielsAlder reaction generally occurs between
Chapter 14, Problem 14(choose chapter or problem)
Although the Diels–Alder reaction generally occurs between an electron rich diene and an electron-deficient dienophile, it is also possible to have inverse-demand Diels–Alder reactions between suitable electrondeicient conjugated double bonds and electron-rich alkenes. These reactions are particularly useful because they allow for the incorporation of heteroatoms into the new six-membered ring. Predict the products of each inverse-demand Diels–Alder reaction below. Be sure your products reflect the correct stereochemistry. If more than one regioisomer is possible, draw both.
Equation Transcription:
Text Transcription:
CH_2
H_2C
H_2C
CO_2CH_3
H_2C
OCH_3
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