One way to determine the number of acidic hydrogens in a molecule is to treat the

Organic Chemistry | 9th Edition | ISBN: 9781305080485 | Authors: John E. McMurry

Problem 22 Chapter 22

Organic Chemistry | 9th Edition

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Organic Chemistry | 9th Edition | ISBN: 9781305080485 | Authors: John E. McMurry

Organic Chemistry | 9th Edition

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Problem 22

One way to determine the number of acidic hydrogens in a molecule is to treat the compound with NaOD in D2O, isolate the product, and determine its molecular weight by mass spectrometry. For example, if cyclohexanone is treated with NaOD in D2O, the product has MW 5 102. Explain how this method works.

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Gen Chem Notes:  Determining rate orders: ­ For this experiment we will solve for the rate orders. ­ To determine A, we will want to look for a spot where A changes but the value of B stays the same. Therefore, we may compare experiments 1 and 2. Between these experiments A doubles, while the rate quadruples. This means that A is a 2 order. ­ To...

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Chapter 22, Problem 22 is Solved
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Textbook: Organic Chemistry
Edition: 9
Author: John E. McMurry
ISBN: 9781305080485

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