Reaction of anthranilic acid (o-aminobenzoic acid) with
Chapter 24, Problem 24(choose chapter or problem)
Reaction of anthranilic acid (o-aminobenzoic acid) with \(\mathrm{HNO}_{2}\) and \(\mathrm{H}_{2} \mathrm{SO}_{4}\) yields a diazonium salt that can be treated with base to yield a neutral diazonium carboxylate.
(a) What is the structure of the neutral diazonium carboxylate?
(b) Heating the diazonium carboxylate results in the formation of \(\mathrm{CO}_{2}, \mathrm{~N}_{2}\), and an intermediate that reacts with 1,3-cyclopentadiene to yield the following product:
What is the structure of the intermediate, and what kind of reaction does it undergo with cyclopentadiene?
Equation Transcription:
Text Transcription:
HNO_2
H_2SO_4
CO_2, N_2
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