Solved: Determine the total entropy change and exergy

Chapter 13, Problem 91P

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QUESTION:

Determine the total entropy change and exergy destruction associated with the process described in Prob. 13–89, using

(a) the ideal-gas approximation and

(b) Kay's rule. Assume constant specific heats and \(T_{0}=30^{\circ} \mathrm{C}\).

Questions & Answers

QUESTION:

Determine the total entropy change and exergy destruction associated with the process described in Prob. 13–89, using

(a) the ideal-gas approximation and

(b) Kay's rule. Assume constant specific heats and \(T_{0}=30^{\circ} \mathrm{C}\).

ANSWER:

Step 1 of 11

a)

Write the entropy balance equation to find the expression of entropy generation in terms of \({O_2}\) and \({N_2}\).

\({S_{in}} - {S_{out}} + {S_{gen}} = \Delta {S_{system}}\)

\(\frac{{{Q_{in}}}}{{{T_{b,surr}}}} + {S_{gen}} = m\left( {{s_2} - {s_1}} \right)\)

\({S_{gen}} = m\left( {{s_2} - {s_1}} \right) - \frac{{{Q_{in}}}}{{{T_{surr}}}}\)

\({S_{gen}} = {m_{{O_2}}}{\left( {{s_2} - {s_1}} \right)_{{O_2}}} + {m_{{N_2}}}{\left( {{s_2} - {s_1}} \right)_{{N_2}}} - \frac{{{Q_{in}}}}{{{T_{surr}}}}\;\;\;\;\;...\;\left( 1 \right)\)

Here, mass of \({O_2}\) is \({m_{{O_2}}}\), mass of \({N_2}\) is \({m_{{N_2}}}\), boundary temperature is \({T_{b,surr}}\), surrounding temperature is\( {T_{surr}}\), entropy at state 1 and 2 is \({s_1}\) and \({s_2}\), entropy generation is \({S_{gen}}\), change in entropy of a system is \(\Delta {S_{system}}\), heat input is \({Q_{in}}\), outlet entropy is \({S_{out}}\), and inlet entropy is \({S_{in}}\).

From the Table of ideal gas specific heats of various common gases, obtain the constant pressure specific heats \(\left( {{c_p}} \right)\) of \({O_2}\) and \({N_2}\) at \(210\;{\rm{K}}\) and \(180\;{\rm{K}}\) as,

\({c_{p,{O_2}@210\;{\rm{K}}}} = 0.918\;\frac{{{\rm{kJ}}}}{{{\rm{kg}} \cdot {\rm{K}}}}\)

\({c_{p,{N_2}@180\;{\rm{K}}}} = 1.039\;\frac{{{\rm{kJ}}}}{{{\rm{kg}} \cdot {\rm{K}}}}\)

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