Single bonds generally experience free rotation at room temperature (as will be
Chapter 2, Problem 2.67(choose chapter or problem)
Single bonds generally experience free rotation at room temperature (as will be discussed in more detail in Chapter 4): Free rotation of single bond Nevertheless, the single bond shown below exhibits a large barrier to rotation. In other words, the energy of the system is greatly increased if that bond is rotated. Explain the source of this energy barrier. (Hint: Think about the atomic orbitals being used to form the conduit.) ! !
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