Consider the following four energy diagrams: Reaction coordinate A B Reaction coordinate

Chapter 6, Problem 6.27

(choose chapter or problem)

Consider the following four energy diagrams: Reaction coordinate A B Reaction coordinate C Reaction coordinate D Reaction coordinate Potential energy Potential energy Potential energy Potential energy (a) Which diagrams correspond with a two-step mechanism? (b) Which diagrams correspond with a one-step mechanism? c) Compare energy diagrams A and C. Which has a relatively larger Ea?(d) Compare diagrams A and C. Which has a negative DG? (e) Compare diagrams A and D. Which has a positive DG? (f) Compare all four energy diagrams. Which one exhibits the largest Ea? (g) Which processes will have a value of Keq that is greater than 1? (h) Which process will have a value of Keq that is roughly equal to 1?

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