Dimethyl ether (CH3OCH3) and ethanol (CH3CH2OH) are constitutional isomers (see Table

Chapter 9, Problem 9.90

(choose chapter or problem)

Dimethyl ether (CH3OCH3) and ethanol (CH3CH2OH) are constitutional isomers (see Table 3.4, p. 113). (a) Use Table 9.2 (p. 371) to calculate DH 8 rxn for the formation of each compound as a gas from methane and oxygen; water vapor also forms. (b) State which reaction is more exothermic. (c) Calculate DH 8 rxn for the conversion of ethanol to dimethyl ether.

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