The release of volatile organic compounds into the atmosphere is regulated to limit

Chapter 13, Problem 13.142

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The release of volatile organic compounds into the atmosphere is regulated to limit ozone formation. In a laboratory simulation, 5% of the ethanol in a liquid detergent is released. Thus, a down-the-drain factor of 0.05 is used to estimate ethanol emissions from the detergent. The kH values for ethanol and 2-butoxyethanol (C4H9OCH2CH2OH) are 531026 atm?m3/mol and 1.631026 atm?m3/mol, respectively. (a) Estimate a downthe-drain factor for 2-butoxyethanol in the detergent. (b) What is the kH for ethanol in units of L?atm/mol? (c) Is this value consistent with a value given as 0.64 Pa?m3/mol?

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