Ionic liquids have many applications in engineering and materials science. The
Chapter 23, Problem 23.121(choose chapter or problem)
Ionic liquids have many applications in engineering and materials science. The dissolution of the metavanadate ion in chloroaluminate ionic liquids has been studied: VO3 2 1 AlCl4 2 - VO2Cl2 2 1 AlOCl2 2 (a) What is the oxidation number of V and Al in each ion? (b) In reactions of V2O5 with HCl, acid concentration affects the product. At low acid concentration, VO2Cl2 2 and VO3 2 form: V2O5 1 HCl - VO2Cl2 2 1 VO3 2 1 H1 At high acid concentration, VOCl3 forms: V2O5 1 HCl - VOCl3 1 H2O Balance each equation, and state which, if either, is a redox process. (c) What mass of VO2Cl2 2 or VOCl3 can form from 12.5 g of V2O5 and the appropriate concentration of acid?
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