(a) Referring to Figure 17.4. describe how you would

Chapter 17, Problem 130AP

(choose chapter or problem)

(a) Referring to Figure 17.4, describe how you would determine the \(\mathrm{p} K_{\mathrm{b}}\) of the base.

(b) Derive an analogous Henderson-Hasselbalch equation relating \(\mathrm{pOH}\) to \(\mathrm{p} K_{\mathrm{b}}\) of a weak base B and its conjugate acid \(\mathrm{HB}^{+}\). Sketch a titration curve showing the variation of the \(\mathrm{pOH}\) of the base solution versus the volume of a strong acid added from a burette. Describe how you would determine the \(\mathrm{p} K_{\mathrm{b}}\) from this curve.

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