(a) When n-heptane burns in a gasoline engine, the combustion process takes place too
Chapter 4, Problem PROBLEM 4-22(choose chapter or problem)
(a) When n-heptane burns in a gasoline engine, the combustion process takes place too quickly. The explosive detonation makes a noise called knocking. When 2,2,4-trimethylpentane (isooctane) is burned, combustion takes place in a slower, more controlled manner. Combustion is a free-radical chain reaction, and its rate depends on the reactivity of the free-radical intermediates. Explain why isooctane has less tendency to knock than does n-heptane. (b) Alkoxy radicals (RO # ) are generally more stable than alkyl (R # ) radicals. Write an equation showing an alkyl free radical (from burning gasoline) abstracting a hydrogen atom from tert-butyl alcohol, (CH 3)3COH. Explain why tert-butyl alcohol works as an antiknock additive for gasoline. (c) Use the information in Table 4-2 (page 167) to explain why toluene (PhCH3) has a very high octane rating of 111. Write an equation to show how toluene reacts with an alkyl free radical to give a relatively stable radical.
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