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Draw the organic products you would expect to isolate from the following reactions

Chapter 10, Problem 10-36

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QUESTION:

Draw the organic products you would expect to isolate from the following reactions (after hydrolysis). (a) (a) MgBr + H2C O (b) (b) MgCl + O (c) (c) CH CH3 CH3 MgI + Ph CHO (d) (d) O OH CH3MgI + (e) CHO + NaBH4 (e) (f) (f ) Ph Ph Ph MgBr + O C (g) (g) 2 Ph MgBr + O O (h) (h) 2 MgCl + Ph O C Cl (i) MgBr O + (i) (j) ( j) CH2 O C OCH3 + NaBH4 O (k) CH2 O C OCH3 + LiAlH4 (k) O (l) (l) (1) Hg(OAc)2, H2O (2) NaBH4 (m) (m) (1) BH3 . THF (2) H2O2, OH (n) (n) H H3C CH2CH2CH3 H C C cold, dilute KMnO4 OH (o) H3O+ (o) H H3C CH2CH2CH3 H C C HCO3H (p) (CH2CH)2CuLi + CH3CH2CHCHCH2Br

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QUESTION:

Draw the organic products you would expect to isolate from the following reactions (after hydrolysis). (a) (a) MgBr + H2C O (b) (b) MgCl + O (c) (c) CH CH3 CH3 MgI + Ph CHO (d) (d) O OH CH3MgI + (e) CHO + NaBH4 (e) (f) (f ) Ph Ph Ph MgBr + O C (g) (g) 2 Ph MgBr + O O (h) (h) 2 MgCl + Ph O C Cl (i) MgBr O + (i) (j) ( j) CH2 O C OCH3 + NaBH4 O (k) CH2 O C OCH3 + LiAlH4 (k) O (l) (l) (1) Hg(OAc)2, H2O (2) NaBH4 (m) (m) (1) BH3 . THF (2) H2O2, OH (n) (n) H H3C CH2CH2CH3 H C C cold, dilute KMnO4 OH (o) H3O+ (o) H H3C CH2CH2CH3 H C C HCO3H (p) (CH2CH)2CuLi + CH3CH2CHCHCH2Br

ANSWER:

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Reactions of organometallic compounds-

Compounds containing a metal attached directly to a carbon atom are called organometallic compounds.

They react with compounds containing different functional groups to form new carbon-carbon bonds.

Organolithium compounds, Grignard reagents are examples of organometallic reagents.

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