ecall from Section 1.9B that there is restricted rotation around carboncarbon double

Chapter 3, Problem 3.51

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ecall from Section 1.9B that there is restricted rotation around carboncarbon double bonds. Maleic acid and fumaric acid are two isomers with vastly different physical properties and pKa values for loss of both protons. Explain why each of these differences occurs. C H HOOC COOH H maleic acid C H H COOH HOOC fumaric acid C C mp (C) 130 286 solubility (g/L) in H2O at 25 C 788 7 pKa1 1.9 3.0 pKa2 6.5 4.5

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