Tertiary alcohols can be formed by the reaction of dimethyl carbonate [(CH3O)2C O] with

Chapter 20, Problem 20.58

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Tertiary alcohols can be formed by the reaction of dimethyl carbonate [(CH3O)2C O] with excess Grignard reagent. Draw a stepwise mechanism for the following transformation. C6H5MgBr + + (excess) dimethyl carbonate CH3O OCH3 H2O O C C6H5 C6H5 CH3OH + HOMgBr C6H5 C OH

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