Sodium borodeuteride (NaBD4) and lithium aluminum deuteride (LiAlD4) are convenient

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Problem 15.2 Chapter 15.2

Organic Chemistry, | 9th Edition

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Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Organic Chemistry, | 9th Edition

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Problem 15.2

Sodium borodeuteride (NaBD4) and lithium aluminum deuteride (LiAlD4) are convenient reagents for introducing deuterium, the mass-2 isotope of hydrogen, into organic compounds. Write the structure of the organic product of the following reactions, clearly showing the position of all the deuterium atoms in each: (a) Reduction of CH3CH O X (acetaldehyde) with NaBD4 in H2O (b) Reduction of CH3CCH3 O X (acetone) with NaBD4 in CH3OD (c) Reduction of C6H5CH O X (benzaldehyde) with NaBD4 in CD3OH (d) Reduction of HCH O X (formaldehyde) with LiAID4 in diethyl ether, followed by addition of D2O

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Chap 17: Equilibrium: The Extent of a Chemical Reaction Equilibrium constant (K): Number equal to a particular ratio of equilibrium concentrations of products to reactants at a particular temperature Law of Chemical equilibrium: At a given temperature, a chemical system reaches a state in which a particular ratio of product to reactant concentrations has a constant value. Reaction quotient:...

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Chapter 15.2, Problem 15.2 is Solved
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Textbook: Organic Chemistry,
Edition: 9
Author: Francis A Carey Dr., Robert M. Giuliano
ISBN: 9780073402741

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