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The epoxide shown gives a mixture of two azido alcohols on reaction with sodium azide in

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano ISBN: 9780073402741 326

Solution for problem 16.15 Chapter 16.12

Organic Chemistry, | 9th Edition

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Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Organic Chemistry, | 9th Edition

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Problem 16.15

The epoxide shown gives a mixture of two azido alcohols on reaction with sodium azide in aqueous acid and in base. O H NaN3, H2O Write a structural formula including stereochemistry for the major product formed at pH 9.5. A different isomer predominates at pH 4.2. What is the structure of this isomer? (Note: The pKa of HN3 = 4.2).

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Friday, February 19, 2016 Chemistry 1102 Notes (2/15-2/19) Chapter 13: Chemical Kinetics - Kinetics - speed/rate at which a reaction takes place • Measured by: - increase in products or - decrease in reactants - Slope & Rate: • Slope = ∆Y/∆X • Rate = ∆ [product] OR [reactant]/∆ t (time in seconds) • Slope = Rate • ∆ [product]...

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Chapter 16.12, Problem 16.15 is Solved
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Textbook: Organic Chemistry,
Edition: 9
Author: Francis A Carey Dr., Robert M. Giuliano
ISBN: 9780073402741

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