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In the presence of the enzyme aconitase, the double bond of aconitic acid undergoes

Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano ISBN: 9780073402741 326

Solution for problem 18.30 Chapter 18

Organic Chemistry, | 9th Edition

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Organic Chemistry, | 9th Edition | ISBN: 9780073402741 | Authors: Francis A Carey Dr., Robert M. Giuliano

Organic Chemistry, | 9th Edition

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Problem 18.30

In the presence of the enzyme aconitase, the double bond of aconitic acid undergoes hydration. The reaction is reversible, and the following equilibrium is established: C HO2C H CH2CO2H CO2H C Aconitic acid (4% at equilibrium) Isocitric acid (C6H8O7) (6% at equilibrium) Citric acid (C6H8O7) (90% at equilibrium) H2O H2O (a) The major tricarboxylic acid present is citric acid, the substance responsible for the tart taste of citrus fruits. Citric acid is achiral. What is its structure? (b) What must be the constitution of isocitric acid? (Assume that no rearrangements accompany hydration.) How many stereoisomers are possible for isocitric acid?

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C127 Lecture 10 Notes- Chemical Kinetics 3-31-16  SECOND AND FINAL FORMAL LAB REPORT  Learning Goals o Be able to determine order for each component of two-component reaction o Be able to properly interpret integrated rate law graphs o Perform calculations to determine rate constant for reaction...

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Chapter 18, Problem 18.30 is Solved
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Textbook: Organic Chemistry,
Edition: 9
Author: Francis A Carey Dr., Robert M. Giuliano
ISBN: 9780073402741

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In the presence of the enzyme aconitase, the double bond of aconitic acid undergoes

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