Give the structure of the principal organic product of each of the following reactions

Chapter 20, Problem 20.41

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Give the structure of the principal organic product of each of the following reactions: (a) Ethyl acetoacetate 1-bromobutane NaOCH2CH3, ethanol (b) Product of part (a) 1. NaOH, H2O 2. H3O 3. heat (c) Acetophenone diethyl carbonate 1. NaOCH2CH3 2. H3O (d) Acetone diethyl oxalate 1. NaOCH2CH3 2. H3O (e) Diethyl malonate 1-bromo-2-methylbutane NaOCH2CH3, ethanol (f) Product of part (e) 1. NaOH, H2O 2. H3O 3. heat (g) Diethyl malonate 6-methyl-2-cyclohexenone NaOCH2CH3, ethanol (h) Product of part (g) H2O, HCl, heat (i) tert-Butyl acetate 1. [(CH3)2CH]2NLi, THF 2. benzaldehyde 3. H3O Problem

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