Uranium tetrafluoride and zirconium tetrafluoride melt at 1035C and 912C, respectively
Chapter 6, Problem 6.14(b)(choose chapter or problem)
Uranium tetrafluoride and zirconium tetrafluoride melt at 1035C and 912C, respectively. They form a continuous series of solid solutions with a minimum melting temperature of 765C and composition x(ZrF4) = 0.77. At 900C, the liquid solution of composition x(ZrF4) = 0.28 is in equilibrium with a solid solution of composition x(ZrF4) = 0.14. At 850C the two compositions are 0.87 and 0.90, respectively. Sketch the phase diagram for this system and state what is observed when a liquid of composition x(ZrF4) = 0.40 is cooled slowly from 900C to 500C.
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