Careful measurements of the emf of the cell Pt
Chapter 7, Problem 7.18(choose chapter or problem)
Careful measurements of the emf of the cell Pt |H2(g, p7) | NaOH(aq, 0.0100 mol kg1), NaCl(aq, 0.01125 mol kg1) | AgCl(s) | Ag have been reported (C.P. Bezboruah, M.F.G.F.C. Camoes, A.K. Covington, and J.V. Dobson, J. Chem. Soc. Faraday Trans. I 69, 949 (1973)). Among the data is the following information: /C 20.0 25.0 30.0 E/V 1.04774 1.04864 1.04942 Calculate pKw at these temperatures and the standard enthalpy and entropy of the autoprotolysis of water at 25.0C.
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