Rydberg molecules are molecules with an electron in an atomic orbital with principal

Chapter 11, Problem 11.11

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Rydberg molecules are molecules with an electron in an atomic orbital with principal quantum number n one higher than the valence shells of the constituent atoms. Speculate about the existence of hyper Rydberg H2 formed from two H atoms with 100s electrons. Make reasonable guesses about the binding energy, the equilibrium internuclear separation, the vibrational force constant, and the rotational constant. Is such a molecule likely to exist under any circumstances?

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