Solution Found!
Phosphorus pentachloride, a key industrial compound with
Chapter 10, Problem 85P(choose chapter or problem)
Phosphorus pentachloride, a key industrial compound with annual world production of about 2 ×107 kg, is used to make other compounds. It reacts with sulfur dioxide to produce phosphorus oxychloride (POCl3) and thionyl chloride (SOCl2). Draw a Lewis structure, and name the molecular shape of each product.
Questions & Answers
QUESTION: Problem 85P
Phosphorus pentachloride, a key industrial compound with annual world production of about 2 ×107 kg, is used to make other compounds. It reacts with sulfur dioxide to produce phosphorus oxychloride (POCl3) and thionyl chloride (SOCl2). Draw a Lewis structure, and name the molecular shape of each product.
ANSWER:
Solution 85P:
Here, we are going to draw a Lewis structure, and name the molecular shape of each product of the following reaction.
Step 1:
The reaction between SO2 and PCl5 is given below:
Lewis structure is the representation of the bonding between atoms of a molecule and the lone pairs of electrons which exist in the molecule.
Lewis structure of POCl3:
Total valence electrons of POCl3 = (5 +6+37) =32 e-
Here, the P atom is surrounded by four electron groups around it. Therefore, its electron-group arrangement is tetrahedral with ideal angle 109.5o.
Thus, the molecular shape of POCl3 is tetrahedral.