Phosphorus pentachloride, a key industrial compound with

Chapter 10, Problem 85P

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QUESTION: Problem 85P

Phosphorus pentachloride, a key industrial compound with annual world production of about 2 ×107 kg, is used to make other compounds. It reacts with sulfur dioxide to produce phosphorus oxychloride (POCl3) and thionyl chloride (SOCl2). Draw a Lewis structure, and name the molecular shape of each product.

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QUESTION: Problem 85P

Phosphorus pentachloride, a key industrial compound with annual world production of about 2 ×107 kg, is used to make other compounds. It reacts with sulfur dioxide to produce phosphorus oxychloride (POCl3) and thionyl chloride (SOCl2). Draw a Lewis structure, and name the molecular shape of each product.

ANSWER:

Solution 85P:

Here, we are going to draw a Lewis structure, and name the molecular shape of each product of the following reaction.

Step 1:

The reaction between SO2 and PCl5 is given below:

Lewis structure is the representation of the bonding between atoms of a molecule and the lone pairs of electrons which exist in the molecule.

Lewis structure of POCl3:

Total valence electrons of POCl3 = (5 +6+37) =32 e-

Here, the P atom is surrounded by four electron groups around it. Therefore, its electron-group arrangement is tetrahedral with ideal angle 109.5o.

Thus, the molecular shape of POCl3 is tetrahedral.


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