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The bond lengths of carbon–carbon, carbon–nitrogen,

Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward ISBN: 9780321696724 27

Solution for problem 100AE Chapter 8

Chemistry: The Central Science | 12th Edition

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Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward

Chemistry: The Central Science | 12th Edition

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Problem 100AE

Problem 100AE

The bond lengths of carbon–carbon, carbon–nitrogen, carbon– oxygen, and nitrogen–nitrogen single, double, and triple bonds are listed in Table 8.5. Plot bond enthalpy (Table 8.4) versus bond length for these bonds (as in Figure 8.17).What do you conclude about the relationship between bond length and bond enthalpy? What do you conclude about the relative strengths of  bonds?

Reference

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Newman projector The eclipsed for has the most torsion strain Torsional: repulsion among electrons in different groups as they pass each other during bond rotation Steric: repulsion between electrons in different groups, but cannot be lessened by bond rotation Angle: bond angles differ from ideal geometry With more C­C bonds, there is less strain such as cyclohexane. All C­H bonds are staggered Twist boat is at the local energy minimum the diagram in chair­chair interconversion of cyclohexane Compound name Asymmetric carbon Stereo center 3 groups present on given carbon All 4 groups must be different to be asymmetric H

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Chapter 8, Problem 100AE is Solved
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Textbook: Chemistry: The Central Science
Edition: 12
Author: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward
ISBN: 9780321696724

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The bond lengths of carbon–carbon, carbon–nitrogen,