Hydrogen sulfide decomposes according to the following

Chapter 17, Problem 40P

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QUESTION:

Problem 40P

Hydrogen sulfide decomposes according to the following reaction, for which Kc= 9.30× 10?8 at 700°C:

2H2S(g) ⇌ 2H2(g) + S2(g)

If 0.45 mol of H2S is placed in a 3.0-L container, what is the equilibrium concentration of H2(g) at 700°C?

Questions & Answers

QUESTION:

Problem 40P

Hydrogen sulfide decomposes according to the following reaction, for which Kc= 9.30× 10?8 at 700°C:

2H2S(g) ⇌ 2H2(g) + S2(g)

If 0.45 mol of H2S is placed in a 3.0-L container, what is the equilibrium concentration of H2(g) at 700°C?

ANSWER:

Solution 40P:

Here, we are going to calculate the equilibrium concentration of H2(g) at 700°C.

Step 1:

Given reaction,

2H2S(g) ⇌ 2H2(g) + S2(g)

Volume = 3.0 L

Moles of H2S =0.45 mol

Therefore, initial [H2S] = =.0.15 M

Let be the concentration of H2(g) and S2 formed after some time. With change in time the concentration of H2S(g) will be reduced by -2x.

Therefore,

At change, [H2] = ,  [S2] =  and [H2S] =

Thus,

At equilibrium,

[HI] = ,   [H2] =   and [S2] =

Hence, the reaction table for the reaction is given below:


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