Average bond enthalpies are generally defined for

Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown

Problem 112IE Chapter 8

Chemistry: The Central Science | 12th Edition

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Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown

Chemistry: The Central Science | 12th Edition

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Problem 112IE

Average bond enthalpies are generally defined for gas-phase molecules. Many substances are liquids in their standard state. (Section) By using appropriate thermochemical data from Appendix C, calculate average bond enthalpies in the liquid state for the following bonds, and compare these values to the gas-phase values given in Table:

Table Average Bond Enthalpies(kJ/mol)

Single Bonds

C–H

413

N–H

391

O–H

463

F–F

155

C–C

348

N–N

163

O—O

146

 

 

C–N

293

N–O

201

O–F

190

Cl–F

253

C–O

358

N–F

272

O–Cl

203

Cl–Cl

242

C–F

485

N–Cl

200

O–l

234

 

 

C–Cl

328

N–Br

243

Br–F

237

 

 

C–Br

276

S–H

339

Br–Cl

218

 

 

C–l

240

H–H

436

S–F

327

Br–Br

193

C–S

259

H–F

567

S–Cl

253

 

 

H–Cl

431

S—Br

218

I–Cl

208

 

 

Si–H

323

H–Br

366

S—S

266

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Textbook: Chemistry: The Central Science
Edition: 12
Author: Theodore E. Brown
ISBN: 9780321696724

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