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Average bond enthalpies are generally defined for

Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward ISBN: 9780321696724 27

Solution for problem 112IE Chapter 8

Chemistry: The Central Science | 12th Edition

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Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward

Chemistry: The Central Science | 12th Edition

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Problem 112IE

Average bond enthalpies are generally defined for gas-phase molecules. Many substances are liquids in their standard state.

(Section 5.7) By using appropriate thermochemical data from Appendix C, calculate average bond enthalpies in the liquid state for the following bonds, and compare these values to the gas-phase values given in Table 8.4:

(a) from Br2(l);

(b) C — Cl, from CCl4(l);

(c) O — O, from H2O2(l) (assume that the O — H bond enthalpy is the same as in the gas phase).

(d) What can you conclude about the process of breaking bonds in the liquid as compared to the gas phase? Explain the difference in the ΔH values between the two phases.

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Chapter 8, Problem 112IE is Solved
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Textbook: Chemistry: The Central Science
Edition: 12
Author: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward
ISBN: 9780321696724

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Average bond enthalpies are generally defined for