A student wants to dissolve the maximum amount of CaF2[Ksp

Chapter 20, Problem 87P

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QUESTION:

Problem 87P

A student wants to dissolve the maximum amount of CaF2[Ksp = 3.2×10–11) to make 1 L of aqueous solution.

(a)        Into which of the following solvents should she dissolve the salt?

(I) Pure water

(II) 0.01 M HF

(III) 0.01 M NaOH

(IV) 0.01 M HCl

(V) 0.01 M Ca(OH)2

(b)   Which would dissolve the least amount of salt?

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QUESTION:

Problem 87P

A student wants to dissolve the maximum amount of CaF2[Ksp = 3.2×10–11) to make 1 L of aqueous solution.

(a)        Into which of the following solvents should she dissolve the salt?

(I) Pure water

(II) 0.01 M HF

(III) 0.01 M NaOH

(IV) 0.01 M HCl

(V) 0.01 M Ca(OH)2

(b)   Which would dissolve the least amount of salt?

ANSWER:

Step 1 of 3

Solubility reaction of is as follows

where  is the solubility-product constant

As fluoride is weak base the following equilibrium reaction can be possible

 

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