A voltaic cell with Mn/Mn2+ and Cd/Cd2+ half-cells has the

Chapter 22, Problem 54P

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Problem 54P

A voltaic cell with Mn/Mn2+ and Cd/Cd2+ half-cells has the following initial concentrations: [Mn2+] = 0.090 M; [Cd2+] = 0.060 M.

(a) What is the initial Ecell?

(b) What is Ecell when [Cd2+] reaches 0.050M?

(c) What is [Mn2+] when Ecell reaches 0.055 V?

(d) What are the equilibrium concentrations of the ions?

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