Consider the change in effective nuclear charge experienced by a 2p electron as we

Chapter 7, Problem 7.87

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Consider the change in effective nuclear charge experienced by a 2p electron as we proceed from C to N. (a) Based on a simple model in which core electrons screen the valence electrons completely and valence electrons do not screen other valence electrons, what do you predict lor the change in Zeff from C to N? (b) What change do you predict using Slater's rules? (c) The actual change in z.11 from C to N is 0.70+. Which approach to estimating Zeu is more accurate? (d) The change in Zeff from N to 0 is smaller than that from C to N. Can you provide an explanation for this observation?

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