The kinetics of this reaction were studied as a function of temperature. (The reaction

Chapter 13, Problem 97

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The kinetics of this reaction were studied as a function of temperature. (The reaction is first order in each reactant and second order overall.) C2H5Br(aq) + OH-(aq) h C2H5OH(l) + Br-(aq) Temperature (C) k(L/mol # s) 25 8.81 * 10-5 35 0.000285 45 0.000854 55 0.00239 65 0.00633 a. Determine the activation energy and frequency factor for the reaction. b. Determine the rate constant at 15 C. c. If a reaction mixture is 0.155 M in C2H5Br and 0.250 M in OH, what is the initial rate of the reaction at 75 C?

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