Sulfide (S2-) salts are notoriously insoluble in aqueous solution. a. Calculate the

Chapter 24, Problem 73

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Sulfide (S2-) salts are notoriously insoluble in aqueous solution. a. Calculate the molar solubility of nickel(II) sulfi de in water. Ksp(NiS) = 3 * 10-16 b. Nickel(II) ions form a complex ion in the presence of ammonia with a formation constant (Kf) of 2.0 * 108 : Ni2+ + 6 NH3 m [Ni(NH3)6] 2+. Calculate the molar solubility of NiS in 3.0 M NH3. c. Explain any differences between the answers to parts a and b .

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