Diethyl ether, C4H10O(l), a flammable compound that has long been used as a surgical

Chapter 15, Problem 5.78

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Diethyl ether, \(\mathrm{C}_4 \mathrm{H}_{10} \mathrm{O}(l)\), a flammable compound that has long been used as a surgical anesthetic, has the structure

                                    \(\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{O}-\mathrm{CH}_2-\mathrm{CH}_3\)

The complete combustion of \(1 \mathrm{~mol}\) of \(\mathrm{C}_4 \mathrm{H}_{10} \mathrm{O}(l)\) to \(\mathrm{CO}_2(g)\) and \(\mathrm{H}_2 \mathrm{O}(l)\) yields \(\Delta H^{\circ}=-2723.7 \mathrm{~kJ}\).

(a) Write a balanced equation for the combustion of \(1 \mathrm{~mol}\) of \(\mathrm{C}_4 \mathrm{H}_{10} \mathrm{O}(l)\).

(b) Write a balanced equation for the formation of \(\mathrm{C}_4 \mathrm{H}_{10} \mathrm{O}(l)\) from its elements.

(c) By using the information in this problem and data in Table 5.3, calculate \(\Delta H_f^{\circ}\) for diethyl ether.

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