Solved: The critical temperatures (K) and pressures (atm) of a series of halogenated

Chapter 18, Problem 11.48

(choose chapter or problem)

The critical temperatures (K) and pressures (atm) of a series of halogenated methanes are as follows:

(a) List the intermolecular forces that occur for each compound.

(b) Predict the order of increasing intermolecular attraction,from least to most,for this series of compounds.

(c) Predict the critical temperature and pressure for \(CCl_4\) based on the trends in this table. Look up the experimentally determined critical temperatures and pressures for \(CCl_4\), using a source such as the CRC Handbook of Chemistry and Physics, and suggest a reason for any discrepancies.

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