Solved: Electric generating plants transport large amounts of hot water through metal

Chapter 6, Problem 6.109

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Electric generating plants transport large amounts of hot water through metal pipes, and oxygen dissolved in the water can cause a major corrosion problem. Hydrazine (N2H4) added to the water avoids the problem by reacting with the oxygen: About 4 107 kg of hydrazine is produced every year by reacting ammonia with sodium hypochlorite in the Raschig process: 2NH3(aq) _ NaOCl(aq) N2H4(aq) _ NaCl(aq) _ H2O(l) _H_rxn _ _151 kJ (a) If _H_f of NaOCl(aq) __346 kJ/mol, find _H_f of N2H4(aq). (b) What is the heat released when aqueous N2H4 is added to 5.00 103 L of plant water that is 2.50 10_4 M O2?

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