Only certain electron transitions are allowed from one energy level to another. In

Chapter 7, Problem 7.100

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Only certain electron transitions are allowed from one energy level to another. In one-electron species, the change in the quantum number l of an allowed transition must be _1. For example, a 3p electron can drop directly to a 2s orbital but not to a 2p. Thus, in the UV series, where nfinal _ 1, allowed electron transitions can start in a p orbital (l _ 1) of n _ 2 or higher, not in an s (l _ 0) or d (l _ 2) orbital of n _ 2 or higher. From what orbital do each of the allowed electron transitions start for the first four emission lines in the visible series (nfinal _ 2)?

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