Solved: The extent of crystal field splitting is often determined from spectra. (a)
Chapter 23, Problem 23.141(choose chapter or problem)
The extent of crystal field splitting is often determined from spectra. (a) Given the wavelength (_) of maximum absorption, find the crystal field splitting energy (_), in kJ/mol, for each of the following complex ions: (b) Construct a spectrochemical series for the ligands in the Cr complexes. (c) Use the Fe data to state how oxidation state affects _. (d) Use the Co, Rh, and Ir data to state how period number affects _. Ion _ (nm) Ion _ (nm) [Cr(H2O)6]3_ 562 [Fe(H2O)6]2_ 966 [Cr(CN)6]3_ 381 [Fe(H2O)6]3_ 730 [CrCl6]3_ 735 [Co(NH3)6]3_ 405 [Cr(NH3)6]3_ 462 [Rh(NH3)6]3_ 295 [Ir(NH3)6]3_ 244
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